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CHIM-F320

Cinétique chimique

academic year
2023-2024

Course teacher(s)

Thierry VISART DE BOCARME (Coordinator)

ECTS credits

5

Language(s) of instruction

french

Course content

Differences between thermodynamics and kinetics. Glossary: reaction rate, stoichiometry, yield, conversion. Material balance for different types of reactors. Kinetic order and molecularity. Rate laws: spillable reactions, influence of concentration. Reversible reactions, parallel and consecutive approximation of the steady state. Expérimental methods, relaxation and quick reactions. Temperature dependence, Arrhenius equation, transition state theory of collisions. Mechanisms of homogeneous reactions. Important examples: chain reactions, polymerization, homogeneous catalysis (acid-base enzyme, metallo-organic). Adsorption. Langmuir isotherm.

Objectives (and/or specific learning outcomes)

Develop basic knowledge of the parameters determining the speed of chemical reactions. Students are expected to know the experimental and theoretical methods of chemical kinetics.

Teaching methods and learning activities

Courses, practical training, exercices

References, bibliography, and recommended reading

“Chemical Kinetics, From Molecular Structure to Chemical Reactivity”, L. Arnaut, S. Formosinho, H. Burrows, 2007, Elsevier

Other information

Contacts

Thierry Visart, Tel. : 02/6503607 Thierry.visart.de.bocarme@ulb.be - Service de Chimie Physique des Matériaux et Catalyse - CP243 - Room P.A.3.121

Evaluation

Method(s) of evaluation

  • Other

Other

Oral examination for the theoretical part. Reports and written examination for the practical part.

Mark calculation method (including weighting of intermediary marks)

80/100 : oral Examination; 20/100 : pratical part, comprising the written examination (1/5 of this pratical part)

Programmes